Biocatalytic Aromaticity-Breaking Epoxidation of Naphthalene and Nucleophilic Ring-Opening Reactions

[Image: see text] Aromatic hydroxylation reactions catalyzed by heme-thiolate enzymes proceed via an epoxide intermediate. These aromatic epoxides could be valuable building blocks for organic synthesis giving access to a range of chiral trans-disubstituted cyclohexadiene synthons. Here, we show tha...

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Publicat a:ACS Catal
Autors principals: Zhang, Wuyuan, Li, Huanhuan, Younes, Sabry H. H., Gómez de Santos, Patricia, Tieves, Florian, Grogan, Gideon, Pabst, Martin, Alcalde, Miguel, Whitwood, Adrian C., Hollmann, Frank
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2021
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7976598/
https://ncbi.nlm.nih.gov/pubmed/33763289
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c05588
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