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Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters

The flourishing Ni/photoredox-catalyzed asymmetric couplings typically rely on redox-neutral reactions. In this work, we report a reductive cross-coupling of aryl iodides and α-chloroboranes under a dual catalytic regime to further enrich the metallaphotoredox chemistry. This approach proceeds under...

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Publié dans:Nat Commun
Auteurs principaux: Zheng, Purui, Zhou, Pan, Wang, Dong, Xu, Wenhao, Wang, Hepan, XU, Tao
Format: Artigo
Langue:Inglês
Publié: Nature Publishing Group UK 2021
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7954797/
https://ncbi.nlm.nih.gov/pubmed/33712612
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-21947-1
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