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Unexpected ortho-Heck Reaction under the Catellani Conditions

An unexpected ortho-Heck reaction has been discovered during the study of palladium/norbornene (Pd/NBE) catalysis. Under the Catellani reaction conditions in the presence of lithium salts and olefins, Heck coupling takes place at the ortho position instead of the commonly observed ipso position; mea...

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Bibliographic Details
Published in:Org Lett
Main Authors: Rago, Alexander J., Dong, Guangbin
Format: Artigo
Language:Inglês
Published: 2020
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7945955/
https://ncbi.nlm.nih.gov/pubmed/32239958
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c00952
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