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Unexpected ortho-Heck Reaction under the Catellani Conditions

An unexpected ortho-Heck reaction has been discovered during the study of palladium/norbornene (Pd/NBE) catalysis. Under the Catellani reaction conditions in the presence of lithium salts and olefins, Heck coupling takes place at the ortho position instead of the commonly observed ipso position; mea...

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書目詳細資料
發表在:Org Lett
Main Authors: Rago, Alexander J., Dong, Guangbin
格式: Artigo
語言:Inglês
出版: 2020
主題:
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7945955/
https://ncbi.nlm.nih.gov/pubmed/32239958
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c00952
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