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Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin-Derived Enol Carbonates

The enantioselective palladium-catalyzed decarboxylative allylic alkylation of fully substituted α-hydroxy acyclic enol carbonates providing tetrasubstituted benzoin derivatives is reported. Investigation into the transformation revealed that preparation of the starting material as a single enolate...

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Bibliografiske detaljer
Udgivet i:Adv Synth Catal
Main Authors: Lavernhe, Rémi, Alexy, Eric J., Zhang, Haiming, Stoltz, Brian M.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7942817/
https://ncbi.nlm.nih.gov/pubmed/33692657
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201901281
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