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Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
The E/Z stereocontrol in a C=C bond is a fundamental issue in olefin synthesis. Although the thermodynamically more stable E geometry is readily addressable by thermal Z to E geometric isomerization through equilibrium, it has remained difficult to undergo thermal geometric isomerization to the reve...
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| Udgivet i: | Nat Commun |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Nature Publishing Group UK
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7935995/ https://ncbi.nlm.nih.gov/pubmed/33674574 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-21720-4 |
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