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Synthesis of N-perfluoroalkyl-3,4-disubstituted pyrroles by rhodium-catalyzed transannulation of N-fluoroalkyl-1,2,3-triazoles with terminal alkynes

The rhodium-catalyzed transannulation of N-perfluoroalkyl-1,2,3-triazoles with aromatic and aliphatic terminal alkynes under microwave heating conditions afforded N-perfluoroalkyl-3,4-disubstituted pyrroles (major products) and N-fluoroalkyl-2,4-disubstituted pyrroles (minor products). The observed...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Bakhanovich, Olga, Khutorianskyi, Viktor, Motornov, Vladimir, Beier, Petr
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7934709/
https://ncbi.nlm.nih.gov/pubmed/33727973
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.17.44
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