In Vitro Assembly as a Tool to Investigate Catalytic Intermediates of [NiFe]-Hydrogenase

[NiFe]-hydrogenases catalyze the reversible reaction H(2) ⇄ 2H(+) + 2e(−). Their basic module consists of a large subunit, coordinating the NiFe(CO)(CN)(2) center, and a small subunit that carries electron-transferring iron-sulfur clusters. Here, we report the in vitro assembly of fully functional [...

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Veröffentlicht in:ACS Catal
Hauptverfasser: Caserta, Giorgio, Lorent, Christian, Pelmenschikov, Vladimir, Schoknecht, Janna, Yoda, Yoshitaka, Hildebrandt, Peter, Cramer, Stephen P., Zebger, Ingo, Lenz, Oliver
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2020
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7932190/
https://ncbi.nlm.nih.gov/pubmed/33680535
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c04079
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