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Structural Characterization of Two CO Molecules Bound to the Nitrogenase Active Site
As an approach towards unraveling the nitrogenase mechanism, we have studied the binding of CO to the active‐site FeMo‐cofactor. CO is not only an inhibitor of nitrogenase, but it is also a substrate, undergoing reduction to hydrocarbons (Fischer–Tropsch‐type chemistry). The C−C bond forming capabil...
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2021
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7920927/ https://ncbi.nlm.nih.gov/pubmed/33320413 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015751 |
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