Versatile Reactivity of Mn(II) Complexes in Reactions with N-Donor Heterocycles: Metamorphosis of Labile Homometallic Pivalates vs. Assembling of Endurable Heterometallic Acetates

Reaction of 2,2′-bipyridine (2,2′-bipy) or 1,10-phenantroline (phen) with [Mn(Piv)(2)(EtOH)](n) led to the formation of binuclear complexes [Mn(2)(Piv)(4)L(2)] (L = 2,2′-bipy (1), phen (2); Piv(−) is the anion of pivalic acid). Oxidation of 1 or 2 by air oxygen resulted in the formation of tetranucl...

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Bibliografiset tiedot
Julkaisussa:Molecules
Päätekijät: Polunin, Ruslan A., Evstifeev, Igor S., Cador, Olivier, Golhen, Stéphane, Gavrilenko, Konstantin S., Lytvynenko, Anton S., Efimov, Nikolay N., Minin, Vadim V., Bogomyakov, Artem S., Ouahab, Lahcène, Kolotilov, Sergey V., Kiskin, Mikhail A., Eremenko, Igor L.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: MDPI 2021
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Article
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC7919295/
https://ncbi.nlm.nih.gov/pubmed/33672016
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26041021
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