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Versatile Reactivity of Mn(II) Complexes in Reactions with N-Donor Heterocycles: Metamorphosis of Labile Homometallic Pivalates vs. Assembling of Endurable Heterometallic Acetates
Reaction of 2,2′-bipyridine (2,2′-bipy) or 1,10-phenantroline (phen) with [Mn(Piv)(2)(EtOH)](n) led to the formation of binuclear complexes [Mn(2)(Piv)(4)L(2)] (L = 2,2′-bipy (1), phen (2); Piv(−) is the anion of pivalic acid). Oxidation of 1 or 2 by air oxygen resulted in the formation of tetranucl...
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| Опубликовано в: : | Molecules |
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| Главные авторы: | , , , , , , , , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
MDPI
2021
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7919295/ https://ncbi.nlm.nih.gov/pubmed/33672016 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26041021 |
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