Breslow Intermediates (Amino Enols) and Their Keto Tautomers: First Gas‐Phase Characterization by IR Ion Spectroscopy

Breslow intermediates (BIs) are the crucial nucleophilic amino enol intermediates formed from electrophilic aldehydes in the course of N‐heterocyclic carbene (NHC)‐catalyzed umpolung reactions. Both in organocatalytic and enzymatic umpolung, the question whether the Breslow intermediate exists as th...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Paul, Mathias, Peckelsen, Katrin, Thomulka, Thomas, Martens, Jonathan, Berden, Giel, Oomens, Jos, Neudörfl, Jörg‐M., Breugst, Martin, Meijer, Anthony J. H. M., Schäfer, Mathias, Berkessel, Albrecht
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898712/
https://ncbi.nlm.nih.gov/pubmed/32893891
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003454
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