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Calcium Hydride Catalysts for Olefin Hydrofunctionalization: Ring‐Size Effect of Macrocyclic Ligands on Activity
The fifteen‐membered NNNNN macrocycle Me(5)PACP (Me(5)PACP=1,4,7,10,13‐pentamethyl‐1,4,7,10,13‐pentaazacyclopentadecane) stabilized the [CaH](+) fragment as a dimer with a distorted pentagonal bipyramidal coordination geometry at calcium. The hydride complex was prepared by protonolysis of calcium d...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Chemistry |
|---|---|
| Prif Awduron: | , , , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
John Wiley and Sons Inc.
2021
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898310/ https://ncbi.nlm.nih.gov/pubmed/33185286 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004931 |
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