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Urea‐Substituted Tetramethylcyclopentadienyl Ligands for Supramolecularly Accelerated Rh(III)‐Catalyzed ortho‐C−H Olefination of Benzoic Acid Derivatives

The design and synthesis of air‐stable and conveniently crystallizable Rh(III)‐cyclopentadienyl catalysts substituted with a urea moiety, which are able to accelerate the C−H olefination of benzoic acid derivatives, is reported. Through kinetic studies and NMR titration experiments, the catalysts’ s...

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Bibliografiske detaljer
Udgivet i:Chemistry
Main Authors: Maurer, David, Breit, Bernhard
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2021
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898290/
https://ncbi.nlm.nih.gov/pubmed/33294985
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202005130
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