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Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and C(sp(3))–H Activation

[Image: see text] The use of the bis(1-piperidinyl)-substituted carbodiphosphorane (Ph(2)(Pip)P)(2)C (1) as an NCN ligand for the stabilization of phosphorus cations was studied. A simple ligand for halide exchange allowed the synthesis and isolation of a series of phosphorus monocations of the type...

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Dettagli Bibliografici
Pubblicato in:Organometallics
Autori principali: Kroll, Alexander, Steinert, Henning, Jörges, Mike, Steinke, Tim, Mallick, Bert, Gessner, Viktoria H.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2020
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7861138/
https://ncbi.nlm.nih.gov/pubmed/33551536
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.0c00412
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