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The “Hidden” Reductive [2+2+1]‐Cycloaddition Chemistry of 2‐Phosphaethynolate Revealed by Reduction of a Th‐OCP Linkage
The reduction chemistry of the newly emerging 2‐phosphaethynolate (OCP)(−) is not well explored, and many unanswered questions remain about this ligand in this context. We report that reduction of [Th(Tren(TIPS))(OCP)] (2, Tren(TIPS)=[N(CH(2)CH(2)NSiPr(i) (3))](3−)), with RbC(8) via [2+2+1] cycloadd...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Angew Chem Int Ed Engl |
|---|---|
| Prif Awduron: | , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
John Wiley and Sons Inc.
2020
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7839465/ https://ncbi.nlm.nih.gov/pubmed/33051949 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012506 |
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