Kinetic and Thermal Study of Ethylene and Propylene Homo Polymerization Catalyzed by ansa-Zirconocene Activated with Alkylaluminum/Borate: Effects of Alkylaluminum on Polymerization Kinetics and Polymer Structure

The kinetics of ethylene and propylene polymerization catalyzed by homogeneous metallocene were investigated using 2-thiophenecarbonyl chloride followed by quenched-flow methods. The studied metallocene catalysts are: rac-Me(2)Si(2-Me-4-Ph-Ind)(2)ZrCl(2) (Mt-I), rac-Et(Ind)(2)ZrCl(2) (Mt-II) activat...

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Detalhes bibliográficos
Publicado no:Polymers (Basel)
Main Authors: Ali, Amjad, Muhammad, Nadeem, Hussain, Shahid, Jamil, Muhammad Imran, Uddin, Azim, Aziz, Tariq, Tufail, Muhammad Khurram, Guo, Yintian, Wei, Tiantian, Rasool, Ghulam, Fan, Zhiqiang, Guo, Li
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2021
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7830494/
https://ncbi.nlm.nih.gov/pubmed/33467427
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym13020268
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