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Kinetic and Thermal Study of Ethylene and Propylene Homo Polymerization Catalyzed by ansa-Zirconocene Activated with Alkylaluminum/Borate: Effects of Alkylaluminum on Polymerization Kinetics and Polymer Structure
The kinetics of ethylene and propylene polymerization catalyzed by homogeneous metallocene were investigated using 2-thiophenecarbonyl chloride followed by quenched-flow methods. The studied metallocene catalysts are: rac-Me(2)Si(2-Me-4-Ph-Ind)(2)ZrCl(2) (Mt-I), rac-Et(Ind)(2)ZrCl(2) (Mt-II) activat...
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| Publicado no: | Polymers (Basel) |
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| Main Authors: | , , , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7830494/ https://ncbi.nlm.nih.gov/pubmed/33467427 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym13020268 |
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