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Kinetic resolution of racemic α-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control
Copolymerization of racemic α-olefins with ethylene and propylene was carried out in the presence of enantiopure C(1)-symmetric ansa metallocene, {1,2-(SiMe(2))(2)(η(5)-C(5)H-3,5-(CHMe(2))(2))(η(5)-C(5)H(3))}ZrCl(2) to probe the effect of the polymer chain end on enantioselection for the R- or S-α-o...
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| Autores principales: | , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
National Academy of Sciences
2006
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1622822/ https://ncbi.nlm.nih.gov/pubmed/17032768 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0603071103 |
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