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Synthesis of tetrafluorinated piperidines from nitrones via a visible-light-promoted annelation reaction

A method for the one-step construction of 3,3,4,4-tetrafluorinated piperidines from nitrones and readily accessible tetrafluorinated iodobromobutane is described. The reaction requires an excess amount of ascorbic acid as the terminal reductant and is performed in the presence of an iridium photocat...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Beilstein J Org Chem
Egile Nagusiak: Supranovich, Vyacheslav I, Dmitriev, Igor A, Dilman, Alexander D
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Beilstein-Institut 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7783028/
https://ncbi.nlm.nih.gov/pubmed/33437323
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.260
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