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Experiments and Direct Dynamics Simulations That Probe η(2)-Arene/Aryl Hydride Equilibria of Tungsten Benzene Complexes
Key steps in the functionalization of an unactivated arene often involve its dihaptocoordination by a transition metal followed by insertion into the C–H bond. However, rarely are the η(2)-arene and aryl hydride species in measurable equilibrium. In this study, the benzene/phenyl hydride equilibrium...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2020
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7778736/ https://ncbi.nlm.nih.gov/pubmed/32842728 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08032 |
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