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Easy Access to Phosphine‐Borane Building Blocks

In this paper, we highlight the synthesis of a variety of primary phosphine‐boranes (RPH(2)⋅BH(3)) from the corresponding dichlorophosphines, simply by using Li[BH(4)] as reductant and provider of the BH(3) protecting group. The method offers facile access not only to alkyl‐ and arylphosphine‐borane...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: de Jong, G. Bas, Ortega, Nuria, Lutz, Martin, Lammertsma, Koop, Slootweg, J. Chris
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756754/
https://ncbi.nlm.nih.gov/pubmed/32602582
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002367
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