Trifluoromethylation of [AuF(3)(SIMes)]: Preparation and Characterization of [Au(CF(3))(x)F(3−x)(SIMes)] (x=1–3) Complexes

Trifluoromethylation of [AuF(3)(SIMes)] with the Ruppert–Prakash reagent TMSCF(3) in the presence of CsF yields the product series [Au(CF(3))(x)F(3−x)(SIMes)] (x=1–3). The degree of trifluoromethylation is solvent dependent and the ratio of the species can be controlled by varying the stoichiometry...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Winter, Marlon, Limberg, Niklas, Ellwanger, Mathias A., Pérez‐Bitrián, Alberto, Sonnenberg, Karsten, Steinhauer, Simon, Riedel, Sebastian
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756667/
https://ncbi.nlm.nih.gov/pubmed/32668044
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002940
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