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Synthesis and Reactivity of Bis(silylene)‐Coordinated Calcium and Divalent Lanthanide Complexes

Divalent lanthanide complexes of Eu (1) and Yb (2) coordinated by a chelating pyridine‐based bis(silylene) ligand were isolated and fully characterized. Compared to the Eu(II) complex 1, the Yb(II) complex 2 presents a lower thermal stability, resulting in the activation of one Si(II)−N bond and for...

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Publicat a:Chemistry
Autors principals: Sun, Xiaofei, Simler, Thomas, Reiter, Kevin, Weigend, Florian, Roesky, Peter W.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756572/
https://ncbi.nlm.nih.gov/pubmed/32744765
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003417
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