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Intramolecular Coupling of Terminal Alkynes by Atom Manipulation

Glaser‐like coupling of terminal alkynes by thermal activation is extensively used in on‐surface chemistry. Here we demonstrate an intramolecular version of this reaction performed by atom manipulation. We used voltage pulses from the tip to trigger a Glaser‐like coupling between terminal alkyne car...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Albrecht, Florian, Rey, Dulce, Fatayer, Shadi, Schulz, Fabian, Pérez, Dolores, Peña, Diego, Gross, Leo
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756451/
https://ncbi.nlm.nih.gov/pubmed/32845044
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009200
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