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Intramolecular Coupling of Terminal Alkynes by Atom Manipulation

Glaser‐like coupling of terminal alkynes by thermal activation is extensively used in on‐surface chemistry. Here we demonstrate an intramolecular version of this reaction performed by atom manipulation. We used voltage pulses from the tip to trigger a Glaser‐like coupling between terminal alkyne car...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Albrecht, Florian, Rey, Dulce, Fatayer, Shadi, Schulz, Fabian, Pérez, Dolores, Peña, Diego, Gross, Leo
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756451/
https://ncbi.nlm.nih.gov/pubmed/32845044
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009200
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