Unraveling the Mechanism of the Ir(III)‐Catalyzed Regiospecific Synthesis of α‐Chlorocarbonyl Compounds from Allylic Alcohols

We have used experimental studies and DFT calculations to investigate the Ir(III)‐catalyzed isomerization of allylic alcohols into carbonyl compounds, and the regiospecific isomerization–chlorination of allylic alcohols into α‐chlorinated carbonyl compounds. The mechanism involves a hydride eliminat...

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Publicat a:Chemistry
Autors principals: Li, Man, Sanz‐Marco, Amparo, Martinez‐Erro, Samuel, García‐Vázquez, Víctor, Mai, Binh Khanh, Fernández‐Gallardo, Jacob, Himo, Fahmi, Martín‐Matute, Belén
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756427/
https://ncbi.nlm.nih.gov/pubmed/32757212
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002845
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