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Unraveling the Mechanism of the Ir(III)‐Catalyzed Regiospecific Synthesis of α‐Chlorocarbonyl Compounds from Allylic Alcohols
We have used experimental studies and DFT calculations to investigate the Ir(III)‐catalyzed isomerization of allylic alcohols into carbonyl compounds, and the regiospecific isomerization–chlorination of allylic alcohols into α‐chlorinated carbonyl compounds. The mechanism involves a hydride eliminat...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756427/ https://ncbi.nlm.nih.gov/pubmed/32757212 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002845 |
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