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[Si(O(2)C(6)F(4))(2)](14): Self‐Assembly of a Giant Perfluorinated Macrocyclic Host by Low‐Barrier Si−O Bond Metathesis
The dynamic covalent self‐assembly of 14 units of bis(perfluorocatecholato)silane leads to [Si(O(2)C(6)F(4))(2)](14)—the first giant perfluorinated macrocycle. The oligomerization process is monitored spectroscopically, and the macrocycle analyzed by single‐crystal X‐ray diffraction. The molecule fo...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756369/ https://ncbi.nlm.nih.gov/pubmed/32786036 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009942 |
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