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Reversible Hydride Migration from C(5)Me(5) to Rh(I) Revealed by a Cooperative Bimetallic Approach

The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing examples of non‐innocent behaviour are being documented. Here, we provide evidence for reversible intramolecular C−H activation at one methy...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Alférez, Macarena G., Moreno, Juan J., Hidalgo, Nereida, Campos, Jesús
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7754342/
https://ncbi.nlm.nih.gov/pubmed/33448577
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202008442
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