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Amino Acid-Based Synthesis and Glycosidase Inhibition of Cyclopropane-Containing Iminosugars
[Image: see text] Synthesis of four iminosugars fused to a cyclopropane ring is described using l-serine as the chiral pool. The key steps are large-scale preparation of an α,β-unsaturated piperidinone followed by completely stereoselective sulfur ylide cyclopropanation. Stereochemistry of compounds...
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| Veröffentlicht in: | ACS Omega |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical Society
2020
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7745444/ https://ncbi.nlm.nih.gov/pubmed/33344836 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c04589 |
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