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A highly efficient glycosidation of glycosyl chlorides using cooperative silver(I) oxide - triflic acid catalysis

Following our discovery that silver(I) oxide-promoted glycosylation with glycosyl bromides can be greatly accelerated in the presence of catalytic TMSOTf or TfOH, reported herein is a new discovery that glycosyl chlorides are even more effective glycosyl donors under these reaction conditions. The d...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Geringer, Scott A., Singh, Yashapal, Hoard, Daniel J., Demchenko, Alexei V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7695998/
https://ncbi.nlm.nih.gov/pubmed/32145116
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905576
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