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A highly efficient glycosidation of glycosyl chlorides using cooperative silver(I) oxide - triflic acid catalysis

Following our discovery that silver(I) oxide-promoted glycosylation with glycosyl bromides can be greatly accelerated in the presence of catalytic TMSOTf or TfOH, reported herein is a new discovery that glycosyl chlorides are even more effective glycosyl donors under these reaction conditions. The d...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Chemistry
Hauptverfasser: Geringer, Scott A., Singh, Yashapal, Hoard, Daniel J., Demchenko, Alexei V.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2020
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7695998/
https://ncbi.nlm.nih.gov/pubmed/32145116
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905576
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