Evaluation of Pd→B Interactions in Diphosphinoborane Complexes and Impact on Inner‐Sphere Reductive Elimination

The dative Pd→B interaction in a series of (R)DPB(R’) Pd(0) and Pd(II) complexes ((R)DPB(R’)=(o‐PR(2)C(6)H(4))(2)BR’, diphosphinoborane) was analyzed using XRD, (11)B NMR spectroscopy and NBO/NLMO calculations. The borane acceptor discriminates between the oxidation state Pd(II) and Pd(0), stabilizi...

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Published in:Chemistry
Main Authors: Ritter, Florian, John, Lukas, Schindler, Tobias, Schroers, Julian P., Teeuwen, Simon, Tauchert, Michael E.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7692930/
https://ncbi.nlm.nih.gov/pubmed/32428264
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001189
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