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Pnictogen-bonding catalysis: brevetoxin-type polyether cyclizations
Pnictogen-bond donors are attractive for use in catalysis because of deep σ holes, high multivalency, rich hypervalency, and chiral binding pockets. We here report natural product inspired epoxide-opening polyether cyclizations catalyzed by fluoroarylated Sb(v) > Sb(iii) > Bi > Sn > Ge....
Tallennettuna:
| Julkaisussa: | Chem Sci |
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| Päätekijät: | , , , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
Royal Society of Chemistry
2020
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7690316/ https://ncbi.nlm.nih.gov/pubmed/33250977 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02551h |
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