Pnictogen-bonding catalysis: brevetoxin-type polyether cyclizations

Pnictogen-bond donors are attractive for use in catalysis because of deep σ holes, high multivalency, rich hypervalency, and chiral binding pockets. We here report natural product inspired epoxide-opening polyether cyclizations catalyzed by fluoroarylated Sb(v) > Sb(iii) > Bi > Sn > Ge....

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Gini, Andrea, Paraja, Miguel, Galmés, Bartomeu, Besnard, Celine, Poblador-Bahamonde, Amalia I., Sakai, Naomi, Frontera, Antonio, Matile, Stefan
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2020
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7690316/
https://ncbi.nlm.nih.gov/pubmed/33250977
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02551h
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