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Conformationally adaptable macrocyclic receptors for ditopic anions: analysis of chelate cooperativity in aqueous containing media

The effect of chelate cooperativity on the binding of several ditopic anions to two tetrathiourea macrocycles has been analysed in competitive solvent mixtures (H(2)O : DMSO 1 : 9 v/v). The semi-flexible receptors bind dicarboxylates with high affinity dependent on the length and flexibility of the...

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Pubblicato in:Chem Sci
Autori principali: Berry, Stuart N., Qin, Lei, Lewis, William, Jolliffe, Katrina A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7690315/
https://ncbi.nlm.nih.gov/pubmed/33250974
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02533j
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