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Picoloyl protecting group in synthesis: focus on a highly chemoselective catalytic removal

The picoloyl ester (Pico) has proven to be a versatile protecting group in carbohydrate chemistry. It can be used for the purpose of stereocontrolling glycosylations via an H-bond-mediated Aglycone Delivery (HAD) method. It can also be used as a temporary protecting group that can be efficiently int...

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Detalhes bibliográficos
Publicado no:Org Biomol Chem
Main Authors: Geringer, Scott A., Mannino, Michael P., Bandara, Mithila D., Demchenko, Alexei V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7656231/
https://ncbi.nlm.nih.gov/pubmed/32608450
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0ob00803f
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