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Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes

An in-depth study of iridium catalysts for the borylation of alkyl C–H bonds is reported. Although the borylation of aryl C–H bonds can be catalyzed by iridium complexes containing phen or bpy ligands at mild temperatures and with limiting arene, the borylation of alkyl C–H bonds remains underdevelo...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Larsen, Matthew A., Oeschger, Raphael J., Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7654975/
https://ncbi.nlm.nih.gov/pubmed/33178481
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c00152
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