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Aerobic Acyloxylation of Allylic C–H Bonds Initiated by a Pd(0) Precatalyst with 4,5-Diazafluoren-9-one as an Ancillary Ligand
Palladium-catalyzed allylic C–H oxidation has been widely studied, but most precedents use acetic acid as the coupling partner. Here, we report a method compatible with diverse carboxylic acid partners. Use of a Pd(0) pre-catalyst under aerobic reaction conditions leads to oxidation of Pd(0) by O(2)...
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| Publicado no: | ChemSusChem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7641472/ https://ncbi.nlm.nih.gov/pubmed/31107593 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cssc.201900727 |
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