Aerobic Acyloxylation of Allylic C–H Bonds Initiated by a Pd(0) Precatalyst with 4,5-Diazafluoren-9-one as an Ancillary Ligand

Palladium-catalyzed allylic C–H oxidation has been widely studied, but most precedents use acetic acid as the coupling partner. Here, we report a method compatible with diverse carboxylic acid partners. Use of a Pd(0) pre-catalyst under aerobic reaction conditions leads to oxidation of Pd(0) by O(2)...

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Bibliographic Details
Published in:ChemSusChem
Main Authors: Kozack, Caitlin V., Sowin, Jennifer A., Jaworski, Jonathan N., Iosub, Andrei V., Stahl, Shannon S.
Format: Artigo
Language:Inglês
Published: 2019
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7641472/
https://ncbi.nlm.nih.gov/pubmed/31107593
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cssc.201900727
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