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Enantiodivergent epoxidation of alkenes with a photoswitchable phosphate manganese-salen complex

The development of enantiodivergent catalysts capable of preparing both enantiomeric products from one substrate in a controlled fashion is challenging. Introducing a switching function into the catalyst can address this challenge, allowing the chiral reaction environment to reversibly change during...

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Publicat a:Nat Synth
Autors principals: Chen, Xiaofei, Gilissen, Pieter J., Tinnemans, Paul, Vanthuyne, Nicolas, Rutjes, Floris P. J. T., Feringa, Ben L., Elemans, Johannes A.A.W., Nolte, Roeland J.M.
Format: Artigo
Idioma:Inglês
Publicat: 2022
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7613796/
https://ncbi.nlm.nih.gov/pubmed/36353682
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s44160-022-00157-7
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