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Observations and comments on the mechanism of epoxidation of alkenes by manganese(III) porphyrins with hypochlorite.

The kinetics of olefin epoxidation in a methylene chloride/water biphase containing a phase-transfer agent with hypochlorite as oxygen transfer reagent and manganese(III) tetraphenylporphyrin catalysts has been reinvestigated. The results do not support the accumulation of an intermediate composed o...

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Detalhes bibliográficos
Main Authors: Lee, R W, Nakagaki, P C, Balasubramanian, P N, Bruice, T C
Formato: Artigo
Idioma:Inglês
Publicado em: 1988
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC279610/
https://ncbi.nlm.nih.gov/pubmed/2829197
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