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Structural Contributions to Autocatalysis and Asymmetric Amplification in the Soai Reaction
Diisopropylzinc alkylation of pyrimidine aldehydes – the Soai reaction, with its astonishing attribute of amplifying asymmetric autocatalysis, occupies a unique position in organic chemistry and stands as an eminent challenge for mechanistic elucidation. A new paradigm of ‘mixed catalyst substrate’...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7597373/ https://ncbi.nlm.nih.gov/pubmed/33108874 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c05994 |
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