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Demystifying the asymmetry-amplifying, autocatalytic behavior of the Soai reaction through structural, mechanistic, and computational studies
The Soai reaction has profoundly impacted chemists’ perspective of chiral symmetry breaking, absolute asymmetric synthesis and its role in the origin of biological homochirality. Herein, we describe the unprecedented observation of asymmetry amplifying autocatalysis in the alkylation of 5-(trimethyl...
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出版年: | Nat Chem |
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主要な著者: | , , , |
フォーマット: | Artigo |
言語: | Inglês |
出版事項: |
2020
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主題: | |
オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7117993/ https://ncbi.nlm.nih.gov/pubmed/32203445 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-020-0421-8 |
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