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Mirror-symmetry breaking in the Soai reaction: A kinetic understanding

Kinetic modeling using nonlinear differential equations is proposed to analyze the spontaneous generation of enantiomeric excess in the autocatalytic addition of diisopropylzinc to prochiral pyrimidine carbaldehydes (Soai reaction). Our approach reproduces experimentally observed giant chiral amplif...

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Main Authors: Islas, Jesús Rivera, Lavabre, Dominique, Grevy, Jean-Michel, Lamoneda, Ramón Hernández, Cabrera, Haydée Rojas, Micheau, Jean-Claude, Buhse, Thomas
Formato: Artigo
Idioma:Inglês
Publicado: National Academy of Sciences 2005
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC1236534/
https://ncbi.nlm.nih.gov/pubmed/16174731
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0503171102
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