Mirror-symmetry breaking in the Soai reaction: A kinetic understanding

Kinetic modeling using nonlinear differential equations is proposed to analyze the spontaneous generation of enantiomeric excess in the autocatalytic addition of diisopropylzinc to prochiral pyrimidine carbaldehydes (Soai reaction). Our approach reproduces experimentally observed giant chiral amplif...

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Detaylı Bibliyografya
Asıl Yazarlar: Islas, Jesús Rivera, Lavabre, Dominique, Grevy, Jean-Michel, Lamoneda, Ramón Hernández, Cabrera, Haydée Rojas, Micheau, Jean-Claude, Buhse, Thomas
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: National Academy of Sciences 2005
Konular:
Physical Sciences
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC1236534/
https://ncbi.nlm.nih.gov/pubmed/16174731
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0503171102
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