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Mirror-symmetry breaking in the Soai reaction: A kinetic understanding
Kinetic modeling using nonlinear differential equations is proposed to analyze the spontaneous generation of enantiomeric excess in the autocatalytic addition of diisopropylzinc to prochiral pyrimidine carbaldehydes (Soai reaction). Our approach reproduces experimentally observed giant chiral amplif...
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| Main Authors: | , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2005
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1236534/ https://ncbi.nlm.nih.gov/pubmed/16174731 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0503171102 |
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