Altering Charges on Heterobimetallic Transition‐Metal Carbonyl Clusters

The homoleptic group 5 carbonylates [M(CO)(6)](−) (M=Nb, Ta) serve as ligands in carbonyl‐terminated heterobimetallic Ag(m)M(n) clusters containing 3 to 11 metal atoms. Based on our serendipitous [Ag(6){Nb(CO)(6)}(4)](2+) (4 a (2+)) precedent, we established access to such Ag(m)M(n) clusters of the...

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Published in:Chemistry
Main Authors: Unkrig, Wiebke, Kloiber, Konstantin, Butschke, Burkhard, Kratzert, Daniel, Krossing, Ingo
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7589396/
https://ncbi.nlm.nih.gov/pubmed/32613683
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002339
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