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Photocatalytic Reductive Radical‐Polar Crossover for a Base‐Free Corey–Seebach Reaction

A metal‐free generation of carbanion nucleophiles is of prime importance in organic synthesis. Herein we report a photocatalytic approach to the Corey–Seebach reaction. The presented method operates under mild redox‐neutral and base‐free conditions giving the desired product with high functional gro...

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Dettagli Bibliografici
Pubblicato in:Chemistry
Autori principali: Donabauer, Karsten, Murugesan, Kathiravan, Rozman, Urša, Crespi, Stefano, König, Burkhard
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7589390/
https://ncbi.nlm.nih.gov/pubmed/32686166
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003000
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