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Periselectivity in the Aza-Diels–Alder Reaction of 1-Azadienes with α-Oxoketenes: A Combined Experimental and Theoretical Study

Inversions in the periselectivity of formal aza-Diels–Alder cycloadditions between α-oxoketenes generated by a thermally-induced Wolff rearrangement and 1-azadienes were observed experimentally as a function of the α-oxoketene and the 1-azadiene, as well as the reaction temperature and time. Some un...

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Vydáno v:Molecules
Hlavní autoři: Presset, Marc, Rajzmann, Michel, Dauvergne, Guillaume, Rodriguez, Jean, Coquerel, Yoann
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7587935/
https://ncbi.nlm.nih.gov/pubmed/33092017
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25204811
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