Photoinduced Formation of Hybrid Aryl Pd-Radical Species Capable of 1,5-HAT: Selective Catalytic Oxidation of Silyl Ethers into Silyl Enol Ethers

A direct visible light-induced generation of a hybrid aryl Pd-radical species from aryl iodide and Pd(0) is reported to enable an unprecedented (for hybrid Pd-radical species) hydrogen atom-transfer event. This approach allowed for efficient desaturation of readily available silyl ethers into synthe...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Parasram, Marvin, Chuentragool, Padon, Sarkar, Dhruba, Gevorgyan, Vladimir
Format: Artigo
Language:Inglês
Published: 2016
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7577783/
https://ncbi.nlm.nih.gov/pubmed/27149524
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b01628
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